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anions for smaller ones in the outer two pockets leads to a relative motion of both [Pd 2 L 4 ] along the common Pd 4 -axis, thereby enlarging the central cavity ( Freye CEJ 2013 ; Dieterich PCCP 2012 ). In [...] structures, as detailed in the following section. Figure 4: Light-triggered processes in stimuli-responsive cages: a) photoisomerization of a DTE based Pd 2 L 4 cage between a guest-binding host and its guest-releasing [...] interacting networks. For example, we could show that moving from homoleptic [Pd 2 L 4 ] cages, featuring coplanar Pd(pyridine) 4 units connected by four banana-shaped ligands of the same chemical structure, …